Orthophosphoric acid contains three relaceable H atoms and it reacts with alkali to form three series of salts. So it is named as triprotic.
H3PO4+NaOH→NaH2PO4Sodiumdihydrogenphosphate+H2O
H3PO4+2NaOH→Na2HPO4Disodiumhydrogenphosphate+2H2O
H3PO4+2NaOH→Na3PO4sodiumphosphate+23H2O