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Introduction to Optical Isomerism

Question

Which of the following coordination compounds would exhibit optical isomerism?
$D i a m m i n e d i c h l o r o p l a t i n u m (I I I)$
$T r a n s - d i c y a n o b i s (e t h y l e n e d i a m i n e) c h r o m i u m (I I I) c h l o r i d e$
$T r i s (e t h y l e n e d i a m i n e) c o b a l t (I I I) b r o m i d e$
$P e n t a a m m i n e n i t r o c o b a l t (I I I) i o d i d e$

A

P e n t a a m m i n e n i t r o c o b a l t (I I I) i o d i d e

B

T r a n s - d i c y a n o b i s (e t h y l e n e d i a m i n e) c h r o m i u m (I I I) c h l o r i d e

C

T r i s (e t h y l e n e d i a m i n e) c o b a l t (I I I) b r o m i d e

D

D i a m m i n e d i c h l o r o p l a t i n u m (I I I)

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Solution

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Optical isomers are mirror images that cannot be superimposed on one another. These are known as enantiomers.
Therefore, $T r i s (e t h y l e n e d i a m i n e) C o b a l t (I I I) b r o m i d e$ shows optical isomerism as:-
(Refer to Image)

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