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Question

Which of the following shows maximum number of isomers?
  1. [Ni(C2O4)(en)2]2
  2. [Cr(SCN)2(NH3)4]+
  3. [Co(NH3)4Cl2]
  4. [Ni(en)(NH3)4]2+

A
[Co(NH3)4Cl2]
B
[Ni(en)(NH3)4]2+
C
[Cr(SCN)2(NH3)4]+
D
[Ni(C2O4)(en)2]2
Solution
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[Cr(SCN)2(NH3)4]+ shows maximum number of isomers. It shows geometrical (cis trans) isomerism as well as linkage isomerism. SCN is ambidentate ligand and can coordinate through either S or N atom.

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