1. CN−:
valence electrons=4+5+1=10
(σ2s)2(σ∗2s)2(σ2p)2(π2p)4
BO=1/2×(6−0)=3;
2. NO:
valence electrons=6+5=11
(σ2s)2(σ∗2s)2(σ2p)2(π2p)4(π∗2p)1
BO=1/2×(6−1)=2.5;
3.O2:
valence electrons=6+6=12
(σ2s)2(σ∗2s)2(σ2p)2(π2p)4(π∗2p)2
BO=1/2×(6−2)=2;
4. N2:
valence electrons=4+5+1=10
(σ2s)2(σ∗2s)2(σ2p)2(π2p)4
BO=1/2×(6−0)=3;
In case of NO, upon removal of one electron from anti-bonding orbital, the bond order increases from 2.5 to 3 and it becomes diamagnetic.