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Question

Reason
The average of four oxidation numbers of sulphurs of the $$S_{4}O_{2-}^{6}$$ is $$2.5.$$.
Assertion
In the species, $$S_{4}O_{6}^{2-}$$ each of the two extreme sulphurs exhibits oxidation state of $$+5$$ and the two middle sulphurs as zero.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
C
Assertion is correct but Reason is incorrect
D
Both Assertion and Reason are incorrect
Solution
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Correct option is B. Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
Structural parameters reveal that the element for whom fractional oxidation state is realised, is present in different oxidation states and different oxidation states are due to different bonding situations.

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