The option (d) represents incorrect statement. It states that
"Removal of electron from orbitals bearing lower n value is easier than from orbital having higher n value".
The correct statement is "Removal of electron from orbitals bearing lower n value is difficult than from orbital having higher n value".
The attraction between the nucleus and the electron present in orbital having lower n value is higher than the attraction between the nucleus and the electron present in orbital having higher n value.