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Question

Which of the following mixture is not a buffer solution?
  1. 100 ml of 0.5 NH4Cl and 100 ml of 0.6 N NH4OH
  2. 100 ml of 0.6 N HCN and 100 ml of 0.4 N NaOH
  3. 100 ml of 0.2 N NH4OH and 100 ml of 0.2 N CH3COOH
  4. 100 ml of 0.4 N HCl and 100 ml of 0.4 N NaOH

A
100 ml of 0.2 N NH4OH and 100 ml of 0.2 N CH3COOH
B
100 ml of 0.6 N HCN and 100 ml of 0.4 N NaOH
C
100 ml of 0.5 NH4Cl and 100 ml of 0.6 N NH4OH
D
100 ml of 0.4 N HCl and 100 ml of 0.4 N NaOH
Solution
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An acidic buffer solution is prepared by mixing a weak acid and its salt with a strong base. A basic buffer solution is prepared by mixing a weak base and its salt with strong acid. A buffer solution cannot be obtained by mixing a strong acid with a strong base.

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