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Question

Light from a discharge tube containing hydrogen atoms falls on the surface of a piece of sodium. The kinetic energy of the fastest photoelectrons emitted from sodium is 0.73 eV, The work function for sodium is 1.82 eV. Find the recoil speed of the emitting atom assuming it to be at rest before the transition.
(Ionization potential of hydrogen is 13.6 eV)
  1. 0.9 m/sec.
  2. 1 m/sec.
  3. 2 m/sec.
  4. 0.8 m/sec.

A
1 m/sec.
B
0.9 m/sec.
C
0.8 m/sec.
D
2 m/sec.
Solution
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The correct option is B 0.8 m/sec.

Solution:
We know that
E0=13.6n2eVatom for atom
Let electron jump from n2 to n1
then
En2En1=13.6n2213.6n22
2.55=13.61n211n22
By hit and trial we get n2=4 and n1=2 [angular momentum m v r = nh2π]
Change in angular momentum = m1h2πm2h2π=h2π(24)=h2π×(2)=hπ
The momentum of emitted photon can be found by de Broge relationship
λhp P=hλ=hvc=Ec
2.55×1.6×10193×108=0.8m/sec


Hence B is the correct option

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