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2H202 alkaline medium *2H20 + 02 the proposed mechanism is as given below : (1) H2O2 +1 → H2O+IO (slow) (2) H202 + 10 + H20+1+02 (fast) (i) Write rate law for the reaction. (ii) Write the overall order of reaction. (iii) Out of steps (1) and (2), which one is rate determining step?

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Similar Questions
Q1
For a reaction
2H2O2I−−−−−−−−alkaline medium2H2O+O2

The proposed mechanism is given below:

(1) H2O2+IH2O+IO(slow)
(2) H2O2+IOH2O+I+O2(fast)

(i) Write rate law for the reaction.
(ii) Write the overall order of the reaction.
(iii) Out of steps (1) and (2), which one is the rate determining step?

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Q2
For a reaction
2H2O2I−−−−−−−−alkaline medium2H2O+O2

The proposed mechanism is given below:

(1) H2O2+IH2O+IO(slow)
(2) H2O2+IOH2O+I+O2(fast)

(i) Write rate law for the reaction.
(ii) Write the overall order of the reaction.
(iii) Out of steps (1) and (2), which one is the rate determining step?
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Q3

write the rate law expression if the mechanism of the reaction
2NO + 2H2 ---> N2 + 2H20

STEP 1 :2NO + H2 ----> N2+ H202 (slow)

step 2 :H202+ H2 ---->2H20

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Q4
Consider decomposition hydrogen peroxide in alkaline medium which is catalysed by iodide ions I-/OH-2H2O2----2H2O+O2 reaction takes place in twos steps:H2O2 + I ---- H2O2 + IO SLOWH2O2 + IO---- H2O + I + O2 FASTWrite the rate law expression and determine the order of reaction w.r.t H2O2.What is the molecularity of each individual step?
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Q5
The reaction: 2NO+2H2N2+2H2O has been assigned to follow the given mechanism:
I. NO+NON2O2 (fast)
II. N2O2+H2N2O+H2O (slow)
III. N2O+H2N2+H2O (fast)
The rate constant of step II is 1.2×104 mol1L min1 while the equilibrium constant of step I is 1.4×102. What is the rate of the reaction when the concentration of NO and H2 each is 0.5 mole L1.

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