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Question

Enthalpy change equal internal energy change when
  1. all the reactants and products are in solution
  2. reaction is carried out in a closed vessel
  3. number of moles of gaseous reactants and that of products is equal
  4. reaction is carried out at constant pressure

A
all the reactants and products are in solution
B
reaction is carried out in a closed vessel
C
number of moles of gaseous reactants and that of products is equal
D
reaction is carried out at constant pressure
Solution
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The correct options are
A all the reactants and products are in solution
B reaction is carried out in a closed vessel
C number of moles of gaseous reactants and that of products is equal
As we know,
ΔH=ΔU+ΔnRT
when
Δn=0=nPnR
ΔH=ΔU
Also, when volume change is negligible, ΔH=ΔU

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