Starch and cellulose both are plant origin. Starch deposits in plant cells, whereas cellulose is most important constituent of plant cell wall. Both starch and cellulose are polymers. Starch is branched polymer of a - D - glucose unit linked by oc - 1, 4 glycosidic bonds. Cellulose is a linear polymer of P - D - glucose unit.
Glucose molecules are present in both starch and cellulose.
Amylose in starch is responsible for the formation of deep blue colour in the presence of iodine. Cellulose does not give any colour at the treatment with iodine, because amylose is absent in cellulose.