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Question

2 moles of PCl5 were heated in a closed vessel of 2 litre capacity. At equilibrium, 40% of PCl5 is dissociated into PCl3 and Cl2. The value of equilibrium constant is-
  1. 0.53
  2. 0.266
  3. 2.66
  4. 5.3

A
5.3
B
2.66
C
0.266
D
0.53
Solution
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PCl5
PCl3
Cl2
Initial
2
0
0
Change
-0.8
0.8
0.8
Equilibrium
1.2
0.8
0.8
Molar concentration
0.6
0.4
0.4

The expression for the equilibrium constant is Kc=[PCl3][Cl2][PCl5]=0.4×0.40.6=0.266.

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