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Question

4 moles of HI is taken in a liter closed vessel and heated to equilibrium. At equilibrium, the concentration of H2 is one mol lit1.

Then the equilibrium constant is:

  1. 4
  2. 0.5
  3. 0.25
  4. 2

A
4
B
0.5
C
2
D
0.25
Solution
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The equilibrium reaction is H2(g) + I2(g)2HI(g).

The number of moles of various species presents initially, and at equilibrium, are given in the following table.


HI
H2I2
Initial
4
0
0
change
-2
1
1
equilibrium
4-2=2
1
1

The expression for the equilibrium constant is Kc=[H2][I2][HI]2.

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