Initial the charge Q=C1V.
After removing the battery the both capacitors are in parallel. So total capacitance C=C1+C2
Let the potential difference across the combination is V′
now charge Q′=CV′=(C1+C2)V′
As the total charge is conserved so Q=Q′⇒C1V=(C1+C2)V′
∴V′=C1VC1+C2