Because the car travels at a constant speed, it has no tangential acceleration, but it does have centripetal acceleration because it travels along a circular arc. The direction of the centripetal acceleration is toward the center of curvature, and the direction of velocity is tangent to the curve.
Point A
direction of velocity: East
direction of the centripetal acceleration: South
Point B
direction of velocity: South
direction of the centripetal acceleration: West