A gaseous alkane on complete combustion gives $$CO_2$$ and $$H_2O.$$ If the ratio of moles of $$O_2$$ needed for combustion and moles of $$CO_2$$ formed is $$5 : 3$$. find out the formula of alkane.
Let the alkane be $$C_nH_{2n + 2}$$
$$C_nH_{2n +2} + \left [ n + \dfrac {n + 1}{2} \right ]O_2 \rightarrow nCO_2 + (n + 1)H_2O$$
$$\dfrac { Mole\,of\,O_2}{Mole\,of\,CO_2} = \dfrac {n + n+1/2}{n} = \dfrac {5}{3}$$
$$n = 3$$
Thus alkane is $$C_3H_8$$.