Answer is C.
As a general rule in electrostatics, electric field lines point in the direction of decreasing electric potential. If a negative charge is initially at rest in an electric field, it will tend to move opposite to the electric field(→F=q→E, where, F is the force vector, q is the charge, and E is the electric field vector). Therefore, a negative charge naturally moves in the direction of increasing potential.
A charge in a pure electric field will follow the tangent of an electric field line.
Therefore, the direction of acceleration of the particle is tangential to the electric line of force at every instant.