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Question

A substitution reaction of methane is:
  1. CH4+Cl2CCl4+HCl
  2. CH4+Cl2CHCl3+HCl
  3. CH4+Cl2CH3Cl+HCl
  4. CH4+Cl2CH2Cl2+HCl

A
CH4+Cl2CHCl3+HCl
B
CH4+Cl2CH2Cl2+HCl
C
CH4+Cl2CCl4+HCl
D
CH4+Cl2CH3Cl+HCl
Solution
Verified by Toppr

When a mixture of methane and chlorine is exposed to ultraviolet light - typically sunlight - a substitution reaction occurs and the organic product is chloromethane. The reaction can be written as: CH4+Cl2CH3Cl+HCl

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Similar Questions
Q1
In which of the following reactions, chlorine acts as an oxidising agent?
(i) CH3CH2OH+Cl2CH3CHO+HCl
(ii) CH3CHO+Cl2CCl3CHO+HCl
(iii) CH4+Cl2CH3Cl+HCl
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Q2
Consider two alternative mechanism for the chlorination of methane. Which step is crucial in deciding which mechanism is not likely to be observed?
Mechanism I Mechanism II
A Cl22Cl
A Cl22Cl
B Cl+CH4HCl+CH3
D Cl+CH4CH3Cl+H
C CH3+Cl2CH3Cl+Cl
E H+Cl2HCl+Cl

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Q3
CH4+Cl2hvCH3Cl+HCl
To obtain high yields of CH3Cl, the ratio of CH4 to Cl2 must be:

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Q4
Consider two alternative mechanisms for the chlorination of methane, Which step is crucial in deciding which mechanism is not likely to be observed?
Mechanism I:
A. Cl22Cl
B. Cl+CH4HCl+CH3
C. ˙CH3+Cl2CH3Cl+Cl
Mechanism II:
D. Cl22Cl
E. Cl+CH4CH3Cl+H
F. H+Cl2HCl+Cl

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Q5
In which of the following reactions chlorine acts an oxidising agent.
i) CH3CH2OH+Cl2CH3CHO+HCl
ii) CH3CHO+Cl2CCl3CHO+HCl
iii) CH4+ClhvCH3Cl+HCl
The correct answer is :

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