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Question

Addition of excess potassium iodide solution to a solution of mercuric chloride gives the halide complex :
  1. tetrahedral K2[HgI4]
  2. linear Hg2I2
  3. trigonal K2[HgI3]
  4. square planar K2[HgCl2I2]

A
square planar K2[HgCl2I2]
B
tetrahedral K2[HgI4]
C
linear Hg2I2
D
trigonal K2[HgI3]
Solution
Verified by Toppr


ΔH=0,HgCl2+4KIK2[HgI4]+2KCl

Hg=[Xe]4f145d106s2

Hg2+=[Xe]4f145d106s0

Hence, the correct option is A

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