Addition of excess potassium iodide solution to a solution of mercuric chloride gives the halide complex :
tetrahedral K2[HgI4]
linear Hg2I2
trigonal K2[HgI3]
square planar K2[HgCl2I2]
A
square planar K2[HgCl2I2]
B
tetrahedral K2[HgI4]
C
linear Hg2I2
D
trigonal K2[HgI3]
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Solution
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ΔH=0,HgCl2+4KI⟶K2[HgI4]+2KCl
Hg=[Xe]4f145d106s2
Hg2+=[Xe]4f145d106s0
Hence, the correct option is A
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