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Question

Adsorption of a gas on solid metal surface is spontaneous and exothermic, then :
  1. ΔH increases
  2. ΔS increases
  3. ΔG increases
  4. ΔS decreases

A
ΔS increases
B
ΔG increases
C
ΔH increases
D
ΔS decreases
Solution
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Adsorption of a gas on solid metal surface is spontaneous and exothermic, then ΔS decreases.
Since for spontaneous and exothermic process, ΔG=ve,ΔH=ve at all temperatures.

Therefore, from ΔG=ΔHTΔS,ΔS should be ve.

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