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Phosphorus - Allotropic Forms

Question

Answer the following question:
What is the structural difference between white phosphorus and red phosphorus.

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Solution

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White phosphorus consists of discrete tetrahedral $$P_{4}$$ molecule with six $$P-P$$ covalent bonds.

Red phosphorus has polymeric structure in which $$P_{4}$$ tetrahedra are linked together through $$P-P$$ covalent bond to form chain.

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