Arrange the following in increasing/decreasing order of boiling point : CH3CH2CH2CH2CH3I,(CH3)2CHCH2CH3II,(CH3)4CIII
I > II > III
II > I > III
III > I > II
III < II < I
A
II > I > III
B
III < II < I
C
III > I > II
D
I > II > III
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Solution
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The decrease order of the boiling point is CH3CH2CH2CH2CH3I>(CH3)2CHCH2CH3II>(CH3)4CIII. As the extent of branching increases, the boiling point decreases.
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