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Question

At certain temperature (T) if the conductivity of pure water is 5.5×107Scm1, then calculate pH of water at given temperature.
Given : λH+=350Scm2sq1;λOH200Scm2eq1;λOH=200Scm2sq1
  1. 6
  2. 7
  3. 8
  4. 5

A
5
B
7
C
8
D
6
Solution
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Conductivity of pure water = 5.5×107Scm1
λH+=350Scm2sq1 λOH=200Scm2sq1
At infinity λ=550Scm2sq1
αOH=λλ=5.5×107550=109
pOH=log(109)=9
pH=149=5

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