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Question

Calculate the emf of the cell
Cr|Cr3+(0.1 M)||Fe2+(0.01 M)|Fe
(Given: ECr3+/Cr=0.75 volt;EFe2+/Fe=0.45 volt).
  1. 1.231 volt
  2. 1.361 volt
  3. 2.461 volt
  4. 2.561 volt

A
2.561 volt
B
1.231 volt
C
1.361 volt
D
2.461 volt
Solution
Verified by Toppr

Cr|Cr3+(0.1M)||Fe2+(0.01M)|Fe
ECr2+|Cr=0.75V;EFe2+/Fe=0.45V
2Cr3++3Fe3Fe2++2Cr
Ecell=EcellRTnFlnQ=1.28.314×2986×96500ln(0.01)3(0.1)2=1.20.00428×ln(104)=1.20.009855×log(104)=1.2+0.0394=1.2394

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Similar Questions
Q1
Calculate the emf of the cell
Cr|Cr3+(0.1 M)||Fe2+(0.01 M)|Fe
(Given: ECr3+/Cr=0.75 volt;EFe2+/Fe=0.45 volt).
View Solution
Q2
Given EoCr3+| Cr =0.72V, EoFe2+|Fe=0.42 V.

The potential for the cell

Cr |Cr3+(0.1M)Fe2+(0.01M)| Fe is:

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Q3
Given, ECr3+/Cr=0.72 V,EFe2+/Fe=0.42 V.
The potential for the cell Cr|Cr3+(0.1 M)||Fe2+(0.01 M)|Fe is:

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Q4
Given ECr3+/Cr=0.72,EFe2+/Fe=0.42 V
The potential for the cell, Cr|Cr3+(0.1M)||Fe2+(0.01M)|Fe is:
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Q5
Calculate e.m.f of the following cell at 298K:
2Cr(s)+3Fe2+(0.1M)2Cr3+(0.01M)+3Fe(s)
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