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Question

Calculate the internal energy at 298K for the formation of one mole of ammonia, if the enthalpy change at constant pressure is 42.0 kJ mol1.
[Given: R=8.314J K1 mol1]

Solution
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N2+3H22NH3

Δn=2(1+3)=2

ΔH=ΔU+ΔnRT

ΔU=ΔHΔnRT

ΔU=42.0 kJ/mol[(2)×8.314×103 kJ/mol/K×298 K]

ΔU=37.0 kJ/mol

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