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Question

Cannizzaro reaction will be given by:
639734_0ef417d8da91425fbd21cb5a359b9514.png
  1. (i), (ii), (iii)
  2. (i) and (ii)
  3. (ii) and (iii)
  4. (i) and (iv)

A
(i) and (iv)
B
(i), (ii), (iii)
C
(i) and (ii)
D
(ii) and (iii)
Solution
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In Cannizzaro reaction aldehydes which do not have α-hydrogen atom undergo self-oxidation and reduction (disproportion) reaction on heating with concentrated alkali.

Compound (i) and (iv) have αH, so they won't undergo Cannizzaro reaction.
Hence, option C is the correct answer.

680359_639734_ans_78c0eae1fa2b48af85fb1a396f526752.png

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