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Question

Carboxylic acids have higher boiling points than aldehydes, ketones and even alcohols of comparable molecular mass. It is due to their _________.
  1. more extensive association of carboxylic acid via van der Waals force of attraction
  2. formation of intramolecular H-bonding
  3. formation of intermolecular H-bonding
  4. formation of carboxylate ion

A
formation of intramolecular H-bonding
B
formation of intermolecular H-bonding
C
formation of carboxylate ion
D
more extensive association of carboxylic acid via van der Waals force of attraction
Solution
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Carboxylic acids have higher boiling points than aldehydes, ketones, and given alcohol of comparable molecular mass. This is because of formation of intermolecular H-bonding.
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