CH4 + O2 + CO2 + 2 H2

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C + O_{2} . ⟶ {C O}_{2} + 94.2 k c a l

H_{2} + \frac{1}{2} O_{2} ⟶ H_{2} + 68.3 k c a l

{C H}_{4} + 2 O_{2} ⟶ {C O}_{2} + 2 H_{2} O + 210.8 k c a l

Then, the heat of formation of methane will be

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2. ${C H}_{4}$ + $O_{2}$ → $C O_{2}$ + $H_{2} O$

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Sone chemical equations are given below.
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$$ CH_4 + 2O_2 \rightarrow CO_2 + 2H_2O $$
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