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Question

Determine [OH] of a 0.050 M solution of ammonia to which has been added sufficient NH4Cl to make the total [NH=4] equal to 0.100.[Kb(NH3)=1.8×105]

Solution
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pKbKb=1.8×105
pKb=5log(1.8)=4.745
pOH=pKb+logSaltbase=4.745log0.1000.050
=4.475log2
pOH=4.4436
[OH]=3.6×105M

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Determine [OH] of a 0.050 M solution of ammonia to which has been added sufficient NH4Cl to make the total [NH=4] equal to 0.100.[Kb(NH3)=1.8×105]
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