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Question

H2O has a higher boiling point than HF. Which among the following is the right reason ?
  1. H2O is more polar than HF
  2. H2O can form more hydrogen bonds
  3. H2O does not have a higher boiling point than HF
  4. H2O has a higher molecular weight
  5. H2O has more atoms

A
H2O is more polar than HF
B
H2O has more atoms
C
H2O can form more hydrogen bonds
D
H2O does not have a higher boiling point than HF
E
H2O has a higher molecular weight
Solution
Verified by Toppr

The correct answer is the option (B).
HF has higher polarity than water as fluorine is more electronegative than oxygen.
In HF molecule, only one H atom can form H bonds whereas in water molecule, two H atoms can form hydrogen bonds. Hence, the number of hydrogen bonds formed by one water molecule is twice the number of hydrogen bonds formed by one HF molecule. Higher is the number of hydrogen bonds, higher is the boiling point.

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