The correct answer is Option D.
Definite article THE is used when we refer to something in particular.
Indefinite article A is used to refer to something in general and when the word begins in a consonant.
Indefinite article AN is used when the word begins in a vowel.
In the given sentence, Statue of Liberty is a particular monument. Thus THE will be used before it.
NEW YORK HARBOUR is a general place but since it is a proper noun, no article will be used before it.
Thus Option D- THE, NO ARTICLE is the correct answer.