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Question

For the following reactions:
Which of the following statements is correct?
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  1. (a) is elimination, (b) and (c) are substitution reactions.
  2. (a) and (b) are elimination reactions and (c) is addition reaction.
  3. (a) is elimination, (b) is substitution and (c) is addition reaction.
  4. (a) is substitution, (b) and (c) are addition reactions.

A
(a) is substitution, (b) and (c) are addition reactions.
B
(a) and (b) are elimination reactions and (c) is addition reaction.
C
(a) is elimination, (b) and (c) are substitution reactions.
D
(a) is elimination, (b) is substitution and (c) is addition reaction.
Solution
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(a) is elimination,
When an alkyl bromide is heated with alcoholic KOH solution, a molecule of HBr is eliminated to form C=C double bond.
(b) is substitution
When secondary alkyl bromide is heated with aqueous KOH, bromine atom is substituted with OH group.
(c) is addition reaction
A molecule of bromine is added across C=C double bond.

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