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>> $For the reaction : PCl5 (g) PCl3 (g) + C$

Question

For the reaction : $P C l_{5} (g) ⇌ P C l_{3} (g) + C l_{2} (g)$
The forward reaction at constant temperature is favoured by:

This question has multiple correct options

A

introducing chlorine gas at constant volume

B

introducing an inert gas at constant pressure

C

increasing the volume of the container

D

introducing $P C l_{5}$ at constant volume

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Updated on : 2022-09-05

Solution

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Correct options are B) , C) and D)

On adding inert gas at constant pressure, effect on equilibrium will be similar to as if volume of container has been increased.

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Consider the reaction, $P C l_{5} (g) ⇌ P C l_{3} (g) + C l_{2} (g)$ in a closed container at equilibrium at a fixed temperature. What will be the effect of adding more $P C l_{5}$ on the equilibrium concentration of $C l_{2} (g)$ ?

Choose the most appropriate answer from the options given below :
a mixture of sand and ammonium chloride can be separated by

For the reaction $P C l_{5} (g) ⇌ P C l_{3} (g) + C l_{2} (g)$ , the forward reaction at constant temperature is favoured by:

For the reaction $P C l_{5} (g) ⇌ P C l_{3} (g) + C l_{2} (g)$ , the forward reaction at constant temperatureis favoured by:

This question has multiple correct options

For $P C l_{5} (g) ⇌ P C l_{3} (g) + C l_{2} (g)$ , if more $C l_{2}$ is added the equilibrium will shift in backward direction. Hence, equilibrium constant will decrease.

Addition of inert gas to the equilibrium mixture at constant volume does not alter the equilibrium.

For $P C l_{5} (g) ⇌ P C l_{3} (g) + C l_{2} (g)$ , if more $C l_{2}$ is added the equilibrium will shift in backward direction. Hence, equilibrium constant will decrease.

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