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Question

For the reaction PCl5(g)PCl3(g)+Cl2(g), the forward reaction at constant temperature is favoured by:
  1. introducing an inert gas at constant volume
  2. introducing chlorine gas at constant volume
  3. introducing an inert gas at constant pressure
  4. increasing the volume of the container

A
introducing chlorine gas at constant volume
B
increasing the volume of the container
C
introducing an inert gas at constant pressure
D
introducing an inert gas at constant volume
Solution
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The correct option is C introducing an inert gas at constant pressure
When an inert gas is introduced at constant pressure, the equilibrium will shift in a direction in which the number of moles increases. This is true for the forward reaction in case of dissociation equilibrium of PCl5.

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