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Question

For the reaction PCl5(g)PCl3(g)+Cl2(g), the forward reaction at constant temperatureis favoured by:
  1. Introducing an inert gas at constant volume.
  2. Introducing chlorine gas at constant volume.
  3. Introducing an inert gas at constant pressure.
  4. Increasing the volume of the container.

A
Introducing an inert gas at constant volume.
B
Introducing an inert gas at constant pressure.
C
Introducing chlorine gas at constant volume.
D
Increasing the volume of the container.
Solution
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When an inert gas is introduced, the reaction will shift in a direction in which the number of moles increases. This happens in the forward reaction. Hence, the equilibrium will shift to right. Also when the volume of the container is increased, the pressure will reduce. To nullify the effect of reduced pressure, the equilibrium will shift to right.

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