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Question

Formation of ClF3 from Cl2 and F2 is an exothermic process. The equilibrium system can be represented as:
Cl2(g)+3F22ClF3; ΔH=329kJ
Which of the following will increase quantity of ClF3 in the equilibrium mixture?
  1. Increase in temperature, decrease in pressure, addition of Cl2
  2. Decrease in temperature and pressure, addition of ClF3
  3. Increase in temperature and pressure, removal of Cl2
  4. Decrease in temperature, increase in pressure, addition of F2

A
Increase in temperature and pressure, removal of Cl2
B
Decrease in temperature and pressure, addition of ClF3
C
Increase in temperature, decrease in pressure, addition of Cl2
D
Decrease in temperature, increase in pressure, addition of F2
Solution
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The correct option is D Decrease in temperature, increase in pressure, addition of F2
Cl2+3F22ClF3;ΔH=329KJ
Since it is releasing energy, it is an exothermic reaction. Exothermic reactions favours making of bonds i.e formation of ClF3, and the reaction proceeds towards rightside at low temperatures, high pressures and also the addition of reactants F2

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Similar Questions
Q1
Formation of ClF3 from Cl2 and F2 is an exothermic process. The equilibrium system can be represented as:
Cl2(g)+3F22ClF3; ΔH=329kJ
Which of the following will increase quantity of ClF3 in the equilibrium mixture?
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Q2
The exothermic formation of ClF3 is represented by the equation: Cl2(g)+3F2(g)2ClF3(g),ΔH=329 kJ
Which of the following will increase the quantity of ClF3 in an equilibrium mixture of Cl2,F2 and ClF3?
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The exothermic equilibrium represented be expression Cl2(g)+3F2(g)2ClF3(g). Which of the following will increase the quantity of ClF3 in an equilibrium mixture of Cl2, F2 and ClF3 ?
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