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Question

Freon 12 is manufactured from $C {C l}_{4}$ by:
Wurtz reaction
Swarts reaction
Fittig reaction
Wurtz-Fittig reaction
Sandmeyer reaction

A

Wurtz reaction

B

Sandmeyer reaction

C

Fittig reaction

D

Wurtz-Fittig reaction

E

Swarts reaction

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Solution

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The correct option is B Swarts reaction
Freon-12 is made by $C {C l}_{4}$ by the Swarts reaction as shown below:

$\begin{matrix} 3 C {C l}_{4} \end{matrix} \begin{matrix} + \end{matrix} \begin{matrix} 2 S b F_{3} \end{matrix} \begin{matrix} ⟶ \end{matrix} \begin{matrix} 3 C {C l}_{2} F_{2} (F r e o n - 12) \end{matrix} \begin{matrix} + \end{matrix} \begin{matrix} 2 S b {C l}_{3} \end{matrix}$

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