Give the decreasing order of reactivity of Diels-Alder reactions for the following :
(IV) > (III) > (I) > (II)
(I) > (II) > (III) > (IV)
(II) > (I) > (III) > (IV)
(IV) > (III) > (II) > (I)
A
(IV) > (III) > (II) > (I)
B
(I) > (II) > (III) > (IV)
C
(II) > (I) > (III) > (IV)
D
(IV) > (III) > (I) > (II)
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Solution
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The decreasing order of reactivity of Diels-Alder reactions is (IV)>(III)>(II)>(I).
The Diels-Alder reaction proceeds faster when dienophiles have electron-withdrawing groups and dienes have an electron-donating group.
Hence, the correct option is B.
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