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Question

Given the ground state energy E0=13.6eV and Bohr radius a0=0.53oA . Find out how the de Broglie wavelength associated with the electron orbiting in the ground state would change when it jumps into the first excited state.

Solution
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rn=a0n2Zrn=0.53n2Z
when the electron is in its ground state:
r1=0.531Z=0.53(Z=1forhydrogenatomforwishE=13.6e
r2=0.53×(2)2=0.53×4FromdeBrogliesrelation:2πrn=nλλ=2πrnn1=2π×0.531=2π×0.53λ=2πr2n2=2π×0.53×42=2π×0.53×2=2λ
Wavelength would get doubled.

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