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Question

How can you explain higher stability of BCl3 as compared to TlCl3?

Solution
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B shows +3 oxidation state and can form stable BCl3. Thallium shows +1 and +3 oxidation state. Due to inert pair effect, +1 oxidation state is more stable than +3 oxidation state. Hence, BCl3 is stable but TlCl3 not.

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