Atomic mass of PbO = 207 + 16 = 223
Atomic mass of HCl = 36.5
Moles of PbO = 6.5223 = 0.029 moles
Moles of HCl = 3.236.5 = 0.088 moles
From the above chemical equation, we see that PbO is the limiting reagent.
∴ 1 mole of PbO gives 1 mole of PbCl2
0.029 moles of PbO forms 0.029 moles of PbCl2.
Hence, the answer is option B.