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Question

How would you account the lower atomic radius of Ga as compared to Al.

Solution
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The lower atomic radius of Ga as compared to Al can be explained on the basis of the presence of 3d series of transition metals. The size of d orbitals is larger than that of p orbitals. This results in poor shielding in d block elements. Hence, the effective nuclear charge of Ga is lower than the expected value. This results in lower atomic radius.

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