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Question

Hydrogen chloride and SO2 are the side products in the reaction of ethanol with thionyl chloride. Which of the following is main product in this reaction?
  1. C2H5OC2H5
  2. C2H5Cl
  3. C2H6
  4. CH3Cl

A
C2H6
B
C2H5OC2H5
C
C2H5Cl
D
CH3Cl
Solution
Verified by Toppr

Chlorination of ethanol is done by using thionyl chloride. The complete reaction is:

C2H5OH+SOCl2C2H5Cl+HCl+SO2

Here, the major product formed is ethyl chloride.
So, the correct option is 'D'.

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