From highest to lowest, the five main layers are :
1) Exosphere: 700 to 10,000 km (440 to 6,200 miles)
2) Thermosphere: 80 to 700 km (50 to 440 miles)
3) Mesosphere: 50 to 80 km (31 to 50 miles)
4) Stratosphere: 12 to 50 km (7 to 31 miles)
5) Troposphere: 0 to 12 km (0 to 7 miles)
Therefore, the order is: III>II>I.
Therefore, correct option is B.