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Question

Identity the compound in which phosphorus exists in the oxidation state of +1.
  1. Phosphonic acid (H3PO3)
  2. Pyrophosphorus acid (H4P2O5)
  3. Orthophosphoric acid (H3PO4)
  4. Phosphinic acid (H3PO2)

A
Phosphonic acid (H3PO3)
B
Phosphinic acid (H3PO2)
C
Pyrophosphorus acid (H4P2O5)
D
Orthophosphoric acid (H3PO4)
Solution
Verified by Toppr

The oxidation state of P atom in phosphonic acid H3PO3 is:
3+x6=0
x=+3.

The oxidation state of P atom in phosphinic acid H3PO2 is:
3+x4=0
x=+1.

The oxidation state of P atom in pyrophosphorus acid H4P2O5 is:
4+x10=0
x=+3.

The oxidation state of P atom in orthophosphoric acid H3PO4 is:
3+x8=0
x=+5.

Hence, option B is correct.

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