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Question

In a 13 L vessel initially following reaction occur : C(s)+S2(g)CS2(g).
At equlibrium 12g=C, 64g=S2 and 76g=CS2 is present at 1027oC temperature then total pressure is:

  1. 200R
  2. 100R
  3. 158R
  4. 79R

A
200R
B
158R
C
100R
D
79R
Solution
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The correct option is A 200R
Solution:- (A) 200R
C(s)+S2(g)CS2(g)

Total no. of gaseous moles =nS2+nCS2=2 moles

Volume (V)=13L
T=1027=(1027+273)K=1300K

Now, from ideal gas equation,
PV=nRT
P=nRTV
P=2×R×130013=200R

Hence the total pressure is 200R.

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