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Question

In pyrophosphoric acid, H4P2O7, number of σ and dπpπ bonds respectively are
  1. 8 and 2
  2. 12 and zero
  3. 6 and 2
  4. 12 and 2

A
6 and 2
B
12 and zero
C
12 and 2
D
8 and 2
Solution
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O=OH|P|OHOOH|P|OH=O

The two double bonds contributes 2 σ and 2 dπpπ.
There are 4 O-H groups = 4 σ bonds
There are 6 P-O type of bonds.

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