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Question

In solid state PCl5 exist as an ionic solid [PCl4]+[PCl6] hybridisation state of cation and anion respectively :
  1. dsp2,sp3d2
  2. sp3,sp3d2
  3. sp3d2,sp3
  4. sp3d2,dsp2

A
dsp2,sp3d2
B
sp3,sp3d2
C
sp3d2,dsp2
D
sp3d2,sp3
Solution
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In the solid state it exists as an ionic solid, [PCl4]+[PCl6]. The cation, [PCl4]+ is tetrahedral and sp3 hybridised. The anion, [PCl6] is octahedral and is sp3d2 hybridised.
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