In solid state $P C l_{5}$ is a :

Question

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Answer 1

In solid state $P C l_{5}$ tries to exist as oppositely charged ions like

(1) $P C l_{4}^{+}$ and (2) $P C l_{6}^{-}$ as the ionic bonding enhances the crystalline nature .

also $P C l_{4}^{+}$ is tetrahedral , while $P C l_{6}^{-}$ is octahedral . these structure fit well into each other which gives more stability to solid structure .
Hence option D is correct.

Answer 2

In solid state $P C l_{5}$ tries to exist as oppositely charged ions like

(1) $P C l_{4}^{+}$ and (2) $P C l_{6}^{-}$ as the ionic bonding enhances the crystalline nature .

also $P C l_{4}^{+}$ is tetrahedral , while $P C l_{6}^{-}$ is octahedral . these structure fit well into each other which gives more stability to solid structure .

Hence option D is correct.

In solid state $P C l_{5}$ is a :

covalent solid

octahedral structure

ionic solid with $[P C l_{6}]^{+}$ octahedral and $[P C l_{4}]^{-}$ tetrahedral

ionic solid with $[P C l_{4}]^{+}$ tetrahedral and $[P C l_{6}]^{-}$ octahedral

In $P C l_{5}$ phosphorus is in $s p^{3} d$ hybridised state but all its five bonds are not equivalent. Justify your answer with reason.

Draw the structure of solid $P C l_{5}$ .

In the solid state $P C l_{5}$ exists as:

$P C l_{5}$ is covalent in gaseous and liquid states but ionic in solid state.

$P C l_{5}$ in solid state consists of tetrahedral $P C l_{4}^{+}$ cation and octahedral $P C l_{6}^{-}$ anion

In solid state $P C l_{5}$ exist as an ionic solid $[P C l_{4}]^{+} [P C l_{6}]^{-}$ hybridisation state of cation and anion respectively :

Revise with Concepts

Compounds of Phosphorus - PCl3

Compounds of Phosphorus - PCl5

In solid state PCl5​ is a :

covalent solid

octahedral structure

ionic solid with [PCl6​]+ octahedral and [PCl4​]− tetrahedral

ionic solid with [PCl4​]+ tetrahedral and [PCl6​]− octahedral

In PCl5​ phosphorus is in sp3d hybridised state but all its five bonds are not equivalent. Justify your answer with reason.

Draw the structure of solid PCl5​.

In the solid state PCl5​ exists as:

PCl5​ is covalent in gaseous and liquid states but ionic in solid state.

PCl5​ in solid state consists of tetrahedral PCl4+​ cation and octahedral PCl6−​ anion

In solid state PCl5​ exist as an ionic solid [PCl4​]+[PCl6​]− hybridisation state of cation and anion respectively :

Revise with Concepts

Compounds of Phosphorus - PCl3

Compounds of Phosphorus - PCl5

In solid state $P C l_{5}$ is a :

ionic solid with $[P C l_{6}]^{+}$ octahedral and $[P C l_{4}]^{-}$ tetrahedral

ionic solid with $[P C l_{4}]^{+}$ tetrahedral and $[P C l_{6}]^{-}$ octahedral

In $P C l_{5}$ phosphorus is in $s p^{3} d$ hybridised state but all its five bonds are not equivalent. Justify your answer with reason.

Draw the structure of solid $P C l_{5}$ .

In the solid state $P C l_{5}$ exists as:

$P C l_{5}$ is covalent in gaseous and liquid states but ionic in solid state.

$P C l_{5}$ in solid state consists of tetrahedral $P C l_{4}^{+}$ cation and octahedral $P C l_{6}^{-}$ anion

In solid state $P C l_{5}$ exist as an ionic solid $[P C l_{4}]^{+} [P C l_{6}]^{-}$ hybridisation state of cation and anion respectively :