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Question

In the reaction sequence:
ASnCl2/HCl−−−−−−BNaNO2/HCl−−−−−−−0oCH2O/Δ−−−C6H5OH, A,B,C are:
  1. benzene, nitrobenzene, aniline
  2. nitrobenzene, aniline, and azo-compound
  3. nitrobenzene, benzene, aniline
  4. benzene, amino compound, aniline

A
benzene, amino compound, aniline
B
benzene, nitrobenzene, aniline
C
nitrobenzene, aniline, and azo-compound
D
nitrobenzene, benzene, aniline
Solution
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The compounds A, B and C are nitrobenzene, aniline and azo-compound.

The reduction of nitrobenzene with SnCl2/HCl gives aniline.

Diazotization of aniline with NaNO2/HCl at low temperature gives benzene diazonium chloride.

When benzene diazonium chloride is heated in presence of water, phenol is obtained.

PhNO2ASnCl2/HCl−−−−−−PhNH2BNaNO2/HCl−−−−−−−0oPhN2ClCH2O/Δ−−−C6H5OH

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Q1
In the reaction sequence:
ASnCl2/HCl−−−−−−BNaNO2/HCl−−−−−−−0oCH2O/Δ−−−C6H5OH, A,B,C are:
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Q2
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Q3
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Q5

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